Modeling of a Solar Heterogeneous Photocatalytic Reactor with TiO2 for Treatment of Wastewater Contaminated By Albendazole

https://doi.org/10.25100/iyc.v21i2.8105
Langmuir-Hinshelwood CPC LVRPA emergent pollutants SFM
Torre empacada: Fotocatalisis

Article Sidebar

pdf xml

Published: Jul 31, 2019
Issue: Vol. 21 No. 2 (2019): Engineering and competitiveness
Section Artículos de investigacion

Publcation metrics

337 | 74 | 4




 


Main Article Content

Authors

María Margarita Guerra Universidad de Cartagena, Departamento de Ingeniería Química, Cartagena, Colombia
  Rodinson Arrieta- Perez Universidad de Puerto Rico, Departamento de Ingeniería Química, San Juan de Puerto Rico, Puerto Rico
  Jose Colina-Marquez Universidad de Cartagena, Departamento de Ingeniería Química, Cartagena, Colombia
Abstract

Albendazole is an anthelmintic drug with antiangiogenic properties, which means that inhibits the development of new blood vessels. This causes a serious risk for the growth of fetus during pregnancy as a result. Heterogeneous photocatalysis has been proposed as an alternative for removal of this contaminant. In this study, a solar compound parabolic collector (CPC) photocatalytic reactor was modeled and simulated in order to describe the total organic carbon (TOC) degradation of commercial albendazole. The Six Flux Model approach (SFM) was used to estimate the Local Velocity Volumetric Rate of Photon Absorption (LVRPA) coupled with a Langmuir-Hinshelwood (L-H) kinetic model in order to describe the photocatalytic degradation of the TOC content of the contaminant and its photochemical oxidation products. The parameters of the L-H model were estimated from experimental data obtained with a catalyst loading of 0.6 g/l, initial pH of 5.0 and three different initial TOC concentrations of the commercial albendazole (159.95, 75.58 and 40 ppm). The rate constant (kT) and adsorption constant (K1), estimated from the parameter fitting, were 9.28×10-4 m1.5ppmW-0.5 s-1 and 3.02 × 10-2 ppm-1, respectively. The model was validated with experimental results, achieving a TOC removal of 40% with the lowest concentration of the contaminant. By simulating the process with different catalyst loadings, the maximum TOC removal was achieved with 0.21 g/L of TiO2.

How to Cite
1.
Guerra MM, Arrieta- Perez R, Colina-Marquez J. Modeling of a Solar Heterogeneous Photocatalytic Reactor with TiO2 for Treatment of Wastewater Contaminated By Albendazole. inycomp [Internet]. 2019 Jul. 31 [cited 2024 Dec. 22];21(2):1-10. Available from: https://revistaingenieria.univalle.edu.co/index.php/ingenieria_y_competitividad/article/view/8105
References

(1) Alfano OM, Cassano, AE. Photoreactor Modeling: Applications to Advanced Oxidation Processes. Int J Chem React Eng [Internet]. 2008;6(1). Available from: https://www.degruyter.com/view/j/ijcre.2008.6.1/ijcre.2008.6.1.1617/ijcre.2008.6.1.1617.xml.

(2) Spasiano D, Marotta R, Malato S, Fernandez-Ibañez P, Somma I Di. Solar photocatalysis: Materials, reactors, some commercial, and pre-industrialized applications. A comprehensive approach. Appl Catal B Environ [Internet]. 2015;170–171:90–123. Doi: 10.1016/j.apcatb.2014.12.050. Available from: https://www.sciencedirect.com/science/article/pii/S0926337315000028.

(3) Méndez-Arriaga F, Maldonado MI, Gimenez J, Esplugas S, Malato S. Abatement of ibuprofen by solar photocatalysis process: Enhancement and scale up. Catal Today [Internet]. 2009;144(1–2):112–6. Doi: 10.1016/j.cattod.2009.01.028. Available from: https://www.sciencedirect.com/science/article/pii/S0920586109000492.

(4) Radjenović J, Sirtori C, Petrović M, Barceló D, Malato S. Solar photocatalytic degradation of persistent pharmaceuticals at pilot-scale: Kinetics and characterization of major intermediate products. Appl Catal B Environ [Internet]. 2009;89(1–2):255–64. Doi: 10.1016/j.apcatb.2009.02.013. Available from: https://www.sciencedirect.com/science/article/pii/S0926337309000666#!.

(5) Puma GL, Puddu V, Tsang HK, Gora A, Toepfer B. Photocatalytic oxidation of multicomponent mixtures of estrogens (estrone (E1), 17β-estradiol (E2), 17α-ethynylestradiol (EE2) and estriol (E3)) under UVA and UVC radiation: Photon absorption, quantum yields and rate constants independent of photon absorp. Appl Catal B Environ [Internet]. 2010;99(3–4):388–97. Doi: 10.1016/j.apcatb.2010.05.015. Available from: https://www.sciencedirect.com/science/article/pii/S0926337310002146.

(6) Kasprzyk-Hordern B, Dinsdale RM, Guwy AJ. The removal of pharmaceuticals, personal care products, endocrine disruptors and illicit drugs during wastewater treatment and its impact on the quality of receiving waters. Water Res [Internet]. 2009;43(2):363–80. Doi: 10.1016/j.watres.2008.10.047. Available from: https://www.sciencedirect.com/science/article/pii/S0043135408005010.

(7) Bistoletti M, Moreno L, Alvarez L, Lanusse C. Multiresidue HPLC method to measure benzimidazole anthelmintics in plasma and egg from laying hens. Evaluation of albendazole metabolites residue profiles. Food Chem [Internet]. 2011;126(2):793–800. Doi: 10.1016/j.foodchem.2010.11.084. Available from: https://www.sciencedirect.com/science/article/pii/S0308814610015025.

(8) Pourgholami MH, Khachigian LM, Fahmy RG, Badar S, Wang L, Chu SWL, et al. Albendazole inhibits endothelial cell migration, tube formation, vasopermeability, VEGF receptor-2 expression and suppresses retinal neovascularization in ROP model of angiogenesis. Biochem Biophys Res Commun [Internet]. 2010;397(4):729–34. Available from: http://dx.doi.org/10.1016/j.bbrc.2010.06.019.

(9) Heberer T. Tracking persistent pharmaceutical residues from municipal sewage to drinking water. J Hydrol [Internet]. 2002;266(3–4):175–89. Doi: 10.1016/S0022-1694(02)00165-8. Available from: https://www.sciencedirect.com/science/article/pii/S0022169402001658.

(10) Méndez-Arriaga F, Esplugas S, Giménez J. Degradation of the emerging contaminant ibuprofen in water by photo-Fenton. Water Res [Internet]. 2010;44(2):589–95. Doi: 10.1016/j.watres.2009.07.009. Available from: https://www.sciencedirect.com/science/article/pii/S0043135409004667.

(11) Papamija M, Sarria V. Degradación fotocatalítica del ibuprofeno empleando dióxido de titanio. Rev Ing [Internet]. 2010;(31):47–53. Doi: 10.16924/riua.v0i31.211. Available from: https://ojsrevistaing.uniandes.edu.co/ojs/index.php/revista/article/view/211.

(12) Cassano AE, Alfano OM. Reaction engineering of suspended solid heterogeneous photocatalytic reactors. Catal Today [Internet]. 2000;58(2–3):167–97. Available from: https://www.sciencedirect.com/science/article/pii/S0920586100002510.

(13) Alfano OM, Bahnemann D, Cassano AE, Dillert R, Goslich R. Photocatalysis in water environments using artificial and solar light. Catal Today [Internet]. 2000;58(2–3):199–230. Available from: https://www.sciencedirect.com/science/article/pii/S0920586100002522.

(14) Toepfer B, Gora A, Puma GL. Photocatalytic oxidation of multicomponent solutions of herbicides: Reaction kinetics analysis with explicit photon absorption effects. Appl Catal B Environ [Internet]. 2006;68(3–4):171–80. Available from: https://www.sciencedirect.com/science/article/pii/S0926337306003171.

(15) Colina-Márquez J, Machuca-Martínez F, Puma GL. Photocatalytic mineralization of commercial herbicides in a pilot-scale solar CPC reactor: Photoreactor modeling and reaction kinetics constants independent of radiation field. Environ Sci Technol [Internet]. 2009;43(23):8953–60. Available from: https://pubs.acs.org/doi/abs/10.1021/es902004b.

(16) Angel-Mueses M, Machuca-Martinez F, Puma GL. Effective quantum yield and reaction rate model for evaluation of photocatalytic degradation of water contaminants in heterogeneous pilot-scale solar photoreactors. Chem Eng J [Internet]. 2013;215–216:937–47. Available from: https://www.sciencedirect.com/science/article/pii/S1385894712015616.

(17) Castilla-Caballero D, Machuca-Martínez F, Bustillo-Lecompte C, Colina-Márquez J. Photocatalytic Degradation of Commercial Acetaminophen: Evaluation, Modeling, and Scaling-Up of Photoreactors. Catalyst [Internet]. 2018;8(5):179. Doi: 10.3390/catal8050179. Available from: https://www.mdpi.com/2073-4344/8/5/179.

(18) Colina-Márquez J, López-Vásquez AF, Machuca-Martínez F. Modeling of direct solar radiation in a compound parabolic collector (CPC) with the Ray Tracing tecnique. DYNA [Internet]. 2010;77(163):132–40. Available from: https://revistas.unal.edu.co/index.php/dyna/article/view/25545/26026.

(19) Malato S. Photocatalytic reactors for the treatment of liquid wastewater in the presence of solar irradiation. In: 1st seminar of “Advanced Oxidation Methods of the Treatment of Liquid and Air Waste” [Internet]. Greece: Aristotle University of Thessaloniki; 2004. Available from: https://www.psa.es/en/projects/cadox/documents/Solarphotoreactors.pdf.

(20) Colina-Márquez J, López-Vásquez AF, Díaz D, Rendón A, Machuca-Martínez F. Photocatalytic Treatment of A Dye Polluted Industrial Effluent With A Solar Pilot-Scale CPC Reactor. J Adv Oxid Technol [Internet]. 2016;12(1):93–99. Available from: https://www.degruyter.com/view/j/jaots.2009.12.issue-1/jaots-2009-0111/jaots-2009-0111.xml.

(21) Puma GL, Brucato A. Dimensionless analysis of slurry photocatalytic reactors using two-flux and six-flux radiation absorption–scattering models. Catal Today [Internet]. 2007;122(1–2):78–90. Doi: 10.1016/j.cattod.2007.01.027. Available from: https://www.sciencedirect.com/science/article/pii/S092058610700051X#!.

(22) Chu C, Churchill S. Multiple scattering by randomly distributed obstacles-Methods of solution. IRE Trans Antennas Propag [Internet]. 1956;4(2):142–8. Doi: 10.1109/TAP.1956.1144373. Available from: https://ieeexplore.ieee.org/document/1144373.

(23) Blanco JG, Malato S, A EC, Bandala ER, Gelover S, Leal T. Purificación de aguas por fotocatálisis heterogénea: Estado del arte. In: Blesa M, editor. CYTED - Eliminación de contaminantes por fotocatálisis heterogénea. Buenos Aires: Universidad Nacional de General San Martín; 2001. p. 51–75.

(24) Colina-Márquez J, Machuca-Martínez F, López-Vásquez AF. Fotodegradación catalítica del pesticida 2,4-d Amina 4. In Seminario Internacional: Gestión integrada de servicios relacionados con el agua en asentamientos nucleados. Santiago de Cali: Universidad del Valle; 2005.

(25) Machuca-Martínez F, Angel-Mueses M, Colina-Márquez J, Puma GL. Photocatalytic Reactor Modeling. In: Schneider J, Bahnemann D, Ye J, Puma GL, Dionysiou DD, editors. Photocatalysis: Fundamentals and Perspectives - Energy and Environment Series [Internet]. Royal Society of Chemistry; 2016. p. 388–424. Doi: 10.1039/9781782622338-00388. Available from: https://pubs.rsc.org/en/content/chapter/bk9781782620419-00388/978-1-78262-041-9.

(26) Angel-Mueses M, Machuca-Martínez F, Hernández-Ramirez A, Puma GL. Effective radiation field model to scattering – Absorption applied in heterogeneous photocatalytic reactors. Chem Eng J [Internet]. 2015;279:442–51. Doi: 10.1016/j.cej.2015.05.056. Available from: https://www.sciencedirect.com/science/article/pii/S1385894715007202.

(27) Ochoa-Gutiérrez KS, Tabares-Aguilar E, Angel-Mueses M, Machuca-Martínez F, Puma GL. A Novel Prototype Offset Multi Tubular Photoreactor (OMTP) for solar photocatalytic degradation of water contaminants. Chem Eng J [Internet]. 2018;341:628–38. Doi: 10.1016/j.cej.2018.02.068. Available from: https://www.sciencedirect.com/science/article/pii/S1385894718302705.

(28) Colina-Márquez J, Machuca-Martínez F, Puma GL. Radiation Absorption and Optimization of Solar Photocatalytic Reactors for Environmental Applications. Environ Sci Technol [Internet]. 2010;44(13):5112–20. Doi: 10.1021/es100130h. Available from: https://pubs.acs.org/doi/abs/10.1021/es100130h.

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.

Authors grant the journal and Universidad del Valle the economic rights over accepted manuscripts, but may make any reuse they deem appropriate for professional, educational, academic or scientific reasons, in accordance with the terms of the license granted by the journal to all its articles.

Articles will be published under the Creative Commons 4.0 BY-NC-SA licence (Attribution-NonCommercial-ShareAlike).