m-Dinitrobenzene hydrogenation using supported platinum catalysts over silica, titania and alumina
Main Article Content
The Pt/SiO2, Pt/Al2O3 y Pt/TiO2 catalysts through wet impregnation at 1% concentration in weigh metal were prepared. The resulting catalysts were characterized by X-ray diffraction (XRD), nitrogen physisorption (77 K) and hydrogen chemisorptions (298 K). Theses catalytic systems were employed in the reaction of m-dinitrobenzene hydrogenation toward m-phenylenediamine. The m-phenylenediamine is aromatic amine used in fine chemicals.
The reactions were carried out in batch reactor to hydrogen pressure of 0.82 MPa, 343 K, using ethanol as solvent. The products resulting were analyzed by gas chromatography. The results showed that Pt/TiO2 catalyst had a high level of selectivity toward m-phenylenediamine (72.4 %) and level of conversion of m-dinitrobenzene (91.5 %). This behavior could be attributed to the strong metal-support interaction, as well as this catalyst is promising by production of m-phenylenediamine.
- Maria H. Brijaldo, Cristian Castillo, Gerónimo Pérez, Main Routes in Hydrogen Production , Ingeniería y Competitividad: Vol. 23 No. 2 (2021): Engineering and Competitiveness
- Hugo A. Rojas, Claudia C. Serrano, Laura V. Vivas, Sucrose inversion on sulfated Zirconia SO42-/ZrO 2 and Niobium Oxide Nb O ·nH O , Ingeniería y Competitividad: Vol. 14 No. 1 (2012): Ingeniería y Competitividad
- Hugo A. Rojas, José J. Martínez, Lizbeth Vargas, Maira I. Alvarado, Gloria Borda, Cinnamaldehyde hydrogenation over Au/ZrO2 and Au/ZrO2-SiO2 catalysts. Support effect and preparation method , Ingeniería y Competitividad: Vol. 14 No. 2 (2012): Ingeniería y Competitividad
Authors grant the journal and Universidad del Valle the economic rights over accepted manuscripts, but may make any reuse they deem appropriate for professional, educational, academic or scientific reasons, in accordance with the terms of the license granted by the journal to all its articles.
Articles will be published under the Creative Commons 4.0 BY-NC-SA licence (Attribution-NonCommercial-ShareAlike).