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The UNIFAC-E activity model, which is a modified expression of their original version for nonelectrolytic systems, has been used to calculate the vapor liquid equilibrium (VLE) of alcohol-waterstrong electrolytes pseudo-binaries systems. The model\'s precision has been confirmed in these systems and could also compare the effect that has on the VLE the addition of a salt, which in some cases has the capacity to move the equilibrium in the wanted sense: total displacement of the azeotrope in azeotropic systems and estrangement of the curve of equilibrium of the line of 45º both in zeotropics and azeotropic systems.

Jimmy Andrés López Jiménez

Estudiante de Ingeniería Química - Departamento de
Ingeniería Química - Universidad Nacional de Colombia -
Manizales.

Herlendy Lozada Salgado

Estudiante de Ingeniería Química - Departamento de
Ingeniería Química - Universidad Nacional de Colombia -
Manizales.
1.
López Jiménez JA, Lozada Salgado H. Equilibrio Líquido Vapor en Sistemas Seudobinarios Alcohol - Agua - Electrolitos Fuertes a partir del Modelo UNIFAC - E. inycomp [Internet]. 2004 Jun. 7 [cited 2024 Dec. 22];6(2):16-24. Available from: https://revistaingenieria.univalle.edu.co/index.php/ingenieria_y_competitividad/article/view/2275