Main Article Content

Authors

Due to the adverse effects that polycyclic aromatic hydrocarbons (PAH) have on the ecosystems of Cartagena Bay. An exergy analysis was carried out to an industrial water treatment process which uses a bioadsorbent from chitosan modified with nanoparticles, to evaluate the energy performance of the process and assess its possible application. The process was simulated in Aspen Plus software and property values ​​of the streams were subtracted for the analysis. In this analysis it was found that the solvent recovery stage shows the highest irreversibilities (284,251.2344 Mj / h), unlike the other stages of the process that presented irreversibilities of the order of 10 ^ 2 (Mj / h), this it is due to the use of thermal energy in the separation equipment that it tends to be lost easily when it is used to do useful work. In addition, a sensitivity analysis was carried out between the adsorption stage and the recovery stage, this indicates that the exergetic efficiency of the adsorption stage increases up to 99%, there is only a 0.1% increase in global efficiency. While an increase of 0.4% in the efficiency of the recovery stage produces a change of 0.4%, this indicates that this stage is crucial to increase the overall exergetic efficiency of the process, which was 15% and shows that
this process presents opportunities for improvement to be completely energy sustainable.

Ángel D. González-Delgado, 1Universidad de Cartagena, Facultad de Ingeniería, Departamento de Ingeniería Química, Grupo de Investigación de Nanopartículas e Ingeniería Asistida por Computador (NIPAC), Cartagena, Colombia.

https://orcid.org/0000-0001-8100-8888

1.
Aguilar-Vásquez EA, González-Delgado Ángel D. Exergy analysis of an industrial process for the removal of polycyclic aromatic hydrocarbons through modified chitosan microbeads. inycomp [Internet]. 2022 May 26 [cited 2024 Nov. 18];24(02):17. Available from: https://revistaingenieria.univalle.edu.co/index.php/ingenieria_y_competitividad/article/view/11113

(1). Godinho JM, Lawhorn J, Boyes BE. Rapid analysis of polycyclic aromatic hydrocarbons. J Chromatogr A [Internet]. 2020;1628:461432. Available from: https://doi.org/10.1016/j.chroma.2020.461432

(2). Health Organization W. Polynuclear aromatic hydrocarbons in Drinking-water Background. Guidelines for Drinkingwater Quality. 2003.

(3). Hussar E, Richards S, Lin Z-Q, Dixon RP, Johnson KA. Human Health Risk Assessment of 16 Priority Polycyclic Aromatic Hydrocarbons in Soils of Chattanooga, Tennessee, USA. Water Air Soil Pollut. 2013;223(9):5535–48.

(4). US Environment Protection Agency. Polycyclic Aromatic Hydrocarbons (PAHs) [Internet]. Environmental Health.2013. Available from: https://www.epa.gov/sites/production/files/2014-03/documents/pahs_factsheet_cdc_2013.pdf

(5). Sun K, Song Y, He F, Jing M, Tang J, Liu R. A review of human and animals exposure to polycyclic aromatic hydrocarbons: Health risk and adverse effects, photo-induced toxicity and regulating effect of microplastics. Sci Total Environ [Internet]. 2021;773:145403. Available from: https://doi.org/10.1016/j.scitotenv.2021.1 45403

(6). Mojiri A, Zhou JL, Ohashi A, Ozaki N, Kindaichi T. Comprehensive review of polycyclic aromatic hydrocarbons in water sources, their effects and treatments. Sci Total Environ [Internet]. 2019;696:133971. Available from: https://doi.org/10.1016/j.scitotenv.2019.133971

(7). Li R, Hua P, Zhang J, Krebs P. Effect of anthropogenic activities on the occurrence of polycyclic aromatic hydrocarbons in aquatic suspended particulate matter: Evidence from Rhine and Elbe Rivers. Water Res [Internet]. 2020;179:115901. Available from: https://doi.org/10.1016/j.watres.2020.115901

(8). Abdel-Shafy HI, Mansour MSM. A review on polycyclic aromatic hydrocarbons: Source, environmental impact, effect on human health and remediation. Egypt J Pet [Internet]. 2016;25(1):107–23. Available from: http://dx.doi.org/10.1016/j.ejpe.2015.03.011

(9). Johnson-Restrepo B, Olivero-Verbel J, Lu S, Guette-Fernández J, Baldiris-Avila R, O’Byrne-Hoyos I, et al. Polycyclic aromatic hydrocarbons and their hydroxylated metabolites in fish bile and sediments from coastal waters of Colombia. Environ Pollut. 2008;151(3):452–9.

(10). Gaurav GK, Mehmood T, Kumar M, Cheng L, Sathishkumar K, Kumar A, etal. Review on polycyclic aromatic hydrocarbons (PAHs) migration from wastewater. J Contam Hydrol [Internet]. 2021;236(May 2020):103715. Available from: https://doi.org/10.1016/j.jconhyd.2020.103715

(11). Costa TC, Hendges LT, Temochko B, Mazur LP, Marinho BA, Weschenfelder SE, et al. Evaluation of the technical and environmental feasibility of adsorption process to remove water soluble organics from produced water: A review. J Pet Sci Eng. 2022;208(April 2021).

(12). Lamichhane S, Bal Krishna KC, Sarukkalige R. Polycyclic aromatic hydrocarbons (PAHs) removal by sorption: A review. Chemosphere [Internet]. 2016;148:336–53. Available from: http://dx.doi.org/10.1016/j.chemosphere. 2016.01.036

(13). Crisafully R, Milhome MAL, Cavalcante RM, Silveira ER, De Keukeleire D, Nascimento RF. Removal of some polycyclic aromatic hydrocarbons from petrochemical wastewater using low-cost adsorbents of natural origin. Bioresour Technol. 2008;99(10):4515–9.

(14). Pal P, Pal A, Nakashima K, Yadav BK. Applications of chitosan in environmental remediation: A review. Chemosphere [Internet]. 2021;266:128934. Available from: https://doi.org/10.1016/j.chemosphere.20 20.128934

(15). Kanmani P, Aravind J, Kamaraj M, Sureshbabu P, Karthikeyan S. Environmental applications of chitosan and cellulosic biopolymers: A comprehensive outlook. Bioresour Technol [Internet]. 2017;242:295–303. Available from: http://dx.doi.org/10.1016/j.biortech.2017. 03.119

(16). Saheed IO, Oh W Da, Suah FBM. Chitosan modifications for adsorption of pollutants – A review. J Hazard Mater [Internet]. 2021;408(December 2020):124889. Available from: https://doi.org/10.1016/j.jhazmat.2020.12 4889

(17). Nisticò R, Franzoso F, Cesano F, Scarano D, Magnacca G, Parolo ME, et al. Chitosan-Derived Iron Oxide Systems for Magnetically Guided and Efficient Water Purification Processes from Polycyclic Aromatic Hydrocarbons. ACS Sustain Chem Eng. 2017;5(1):793–801.

(18). Solano RA, De León LD, De Ávila G, Herrera AP. Polycyclic aromatic hydrocarbons (PAHs) adsorption from aqueous solution using chitosan beads modified with thiourea, TiO2 and Fe3O4 nanoparticles. Environ Technol Innov [Internet]. 2021;21:101378. Available from: https://doi.org/10.1016/j.eti.2021.101378

(19). Oliveira RVM, Lima JRA, Cunha G da C, Romão LPC. Use of eco-friendly magnetic materials for the removal of polycyclic aromatic hydrocarbons and metals from environmental water samples. J Environ Chem Eng [Internet]. 2020;8(4):104050. Available from: https://doi.org/10.1016/j.jece.2020.10405 0

(20). Nisticò R, Cesano F, Franzoso F, Magnacca G, Scarano D, Funes IG, et al. From biowaste to magnet-responsive materials for water remediation from polycyclic aromatic hydrocarbons. Chemosphere. 2018;202:686–93.

(21). Zhang Y, Zhao M, Cheng Q, Wang C, Li H, Han X, et al. Research progress of adsorption and removal of heavy metals by chitosan and its derivatives: A review. Chemosphere [Internet]. 2021;279(May):130927. Available from: https://doi.org/10.1016/j.chemosphere.2021.130927

(22). Sirajudheen P, Chettithodi N, Vigneshwaran S, Chelaveettil BM, Meenakshi S. Applications of chitin and chitosan based biomaterials for the adsorptive removal of textile dyes from water — A comprehensive review. Carbohydr Polym. 2021;273(July).

(23). Meramo-Hurtado SI, Moreno-Sader KA, González-Delgado ÁD. Design, Simulation, and Environmental Assessment of an Adsorption-Based Treatment Process for the Removal of Polycyclic Aromatic Hydrocarbons (PAHs) from Seawater and Sediments in North Colombia. ACS Omega. 2020;5(21):12126–35.

(24). Querol E, Gonzalez-Regueral B, PerezBenedito JL. Enfoque Práctico de Exergia y Análisis Termoeconómico de Procesos Industriales [Internet]. 2013. 93 p. Available from: http://www.springer.com/series/8903

(25). Van Gool W. Thermodynamics of chemical references for exergy analysis. Energy Convers Manag. 1998;39(16– 18):1719–28.

(26). de Oliveira S. Exergy: Production, cost and renewability. Vol. 63, Green Energy and Technology. 2013.

(27). Dincer I, Rosen MA. Exergy. Energy, Environment And Sustainable Development. Second. San Diego: Elsevier; 2013.

(28). Aghbashlo M, Mobli H, Rafiee S, Madadlou A. A review on exergy analysis of drying processes and systems. Renew Sustain Energy Rev [Internet]. 2013;22:1–22. Available from: http://dx.doi.org/10.1016/j.rser.2013.01.0 15

(29). Wittig WA, Jeng H. Exergy: Energy, Environment and Sustainable Development. 2005;1–6.

(30). Meramo-Hurtado S, Alarcón-Suesca C, González-Delgado ÁD. Exergetic sensibility analysis and environmental evaluation of chitosan production from shrimp exoskeleton in Colombia. J Clean Prod. 2020;248.

(31). Sato N. Chemical Energy and Exergy: An Introduction to Chemical Thermodynamics for Engineers. Chemical Energy and Exergy: An Introduction to Chemical Thermodynamics for Engineers. 2004. 1– 149 p.

(32) Rivero R, Garfias M. Standard chemical exergy of elements updated. Energy. 2006;31(15):3310–26.

(33). Michalakakis C, Cullen JM, Gonzalez Hernandez A, Hallmark B. Exergy and network analysis of chemical sites. Sustain Prod Consum [Internet]. 2019;19:270–88. Available from: https://doi.org/10.1016/j.spc.2019.07.004

(34). Arshad A, Ali HM, Habib A, Bashir MA, Jabbal M, Yan Y. Energy and exergy analysis of fuel cells: A review. Therm Sci Eng Prog. 2019;9:308–21.

(35). Meramo-Hurtado S, Urbina-Suaréz N, González-Delgado Á. Computer-aided environmental and exergy analyses of a large-scale production of chitosan microbeads modified with TiO2 nanoparticles. J Clean Prod. 2019;237.

(36). Meramo-Hurtado S, Herrera-Barros A, González-Delgado Á. Evaluation oflargescale production of chitosan microbeads modified with nanoparticles based on exergy analysis. Energies. 2019;12(79).

Received 2021-03-31
Accepted 2021-11-21
Published 2022-05-26